Archive for May, 2006

The war on the next generation of scientists

Tuesday, May 30th, 2006

Much to my parents’ dismay, when I was a small child, I was a an amateur chemist. Not having much in the way of chemical glassware, I would mix various things in the toilet to see what would happen. This, more often than not, produced amusing rather than toxic results. Amusing, that is, unless you were the one who had to clean up afterwards!

While I soon graduated to crystals in jars, ripping apart electronics, and putting them back together again (occasionally successfully), I eventually came back to chemistry and got a degree in it – then started teaching it.

Even in my youth, though, the chemistry set was on the decline (hence the reason for putting reagents into the big white bowl with convenient “waste disposal” lever). Too dangerous, they said. You can’t let kids play with magnesium ribbon! They could poke their eyes out! Or blow up the house! Or whatever the heck that stuff does …

So I have a certain affinity for household chemistry, and articles like this one in Wired disturb me. There’s a drive on – spurred by the unavoidable fact that chemicals can be dangerous coupled with the mad desire for protection from terrorism and drugs – to legislate the amateur chemist out of existence. The elimination of budding scientists might not be the intention of the criminalization of amateur science, but consider this: Almost everything that causes an interesting chemical effect can be dangerous. Take away everytihng that’s potentially dangerous and/or could potentially be used to make some kind of drug and you have … nothing.

Want proof? Take a look in the Wired article:

more than 30 states have passed laws to restrict sales of chemicals and lab equipment associated with meth production, which has resulted in a decline in domestic meth labs, but makes things daunting for an amateur chemist shopping for supplies. It is illegal in Texas, for example, to buy such basic labware as Erlenmeyer flasks or three-necked beakers without first registering with the state’s Department of Public Safety to declare that they will not be used to make drugs. Among the chemicals the Portland, Oregon, police department lists online as “commonly associated with meth labs” are such scientifically useful compounds as liquid iodine, isopropyl alcohol, sulfuric acid, and hydrogen peroxide, along with chemistry glassware and pH strips. Similar lists appear on hundreds of Web sites.

I’ve bolded the ridiculously common items here. Iodine, rubbing alcohol (isopropyl alcohol), and hydrogen peroxide can be found in most medicine cabinets. Got an aquarium or pool? You’ll need the pH strips. (Not mentioned on this list, but another household compound associated with meth is pseudoephedrine – found in Sudafed.)

Sulfuric acid’s one of the most common compounds in the world – you’ll find it in your car battery. And here’s a hint to overzealous legislators: Erlenmeyer flasks are not actually required to make drugs, but they sure do make simple kid-level experiments like titration of household vinegar easier.

So heaven help you if you have a car, a pool, an inquisitive kid, and a reasonably stocked medicine cabinet. You’re probably on someone’s watch list!

Tom, Star Hustler

Sunday, May 28th, 2006

Tom channels Jack Horkheimer, Star Hustler!

[Keep looking up!]
Keep … looking … up!

The wheat and the chaff

Saturday, May 27th, 2006

Many college-level science courses begin with what, for the students, should be a brief review of the basics of the scientific method. After all, without any hint of the method behind the science in a course, a science course becomes a jumble of facts to memorize and regurgitate on command.

Sometimes, though, these beginning exercises in the methods of science can turn into frustration for instructors, who have to wrestle with the deficiencies of students in other areas. In particular, many students aren’t able to separate needed information from unneeded information.

Here’s an example.

The assignment:

You wake up one morning to find the power is off in your home. There can be a number of reasons for no power…I’ll let your imagination run wild as to the other observations that you might make to help you figure out the cause. Formulate 1) a hypothesis and 2) a prediction based on your observations; post them as a reply to this message.

As you can see, this isn’t exactly a foreign situation to anyone who lives in a modern home with lights and electricity.

Here’s one of the responses:

I woke up late for work one morning because the alarm clock didn’t go off. When I looked at my cell phone to see the time, I immediatly jumped out of bed and threw the light switch up, no light. I went in the bathroom and threw that switch up, no light there either. The power was out. I do remember hearing thunder last night and I know that there were severe thunderstorm warnings and watches all around until late into the night. The storm must have caused there to be a power outage and the power company had not yet been notified. I quickly got dressed and flew out the house. On the way to work I called the power company to report the outage. Thank goodness for cell phones.

So what’s wrong with the response? Well, other than the fact that the imagery associated with the phrase “I went in the bathroom and threw that switch up” reminds me of the ipecac scene in an old episode of Family Guy, I don’t think the point of the assignment was to write a short essay in praise of the cellular phone. You could actually make a few hypotheses and predictions from what this student has written, but the student doesn’t actually point any of them out.

While this particular example isn’t from any of my classes, I do run into a lot of the same kinds of answers. Students have an inability to extract relevant information. It’s no wonder that these students have trouble with the sciences, where stripping away unimportant detail is fundamental to explaining why things work.

But why do students have these problems? Is it a lack of training in early years? (Is the problem-solving that students do in high school so contrived that students never have to actually think about details and whether they are important?) Is the “info dump” style of answering questions (as demonstrated above) rewarded somewhere along the line? (I’m thinking that partial credit might play a role here.)

Any ideas?

Old School Chemistry – The Analysis of Native Gold

Friday, May 26th, 2006

I have a small (but growing) collection of chemistry books from the 1800s and early 1900s. If you’re a student of chemistry, it’s nice to have an idea of the science’s roots. These old books help to show how the science has matured over the years.

J.L Comstock’s Elements of Chemistry textbook (1851 edition, pages 388-389) provides us with a method for analyzing the composition of native gold – that is, gold as you might find it in the ground. If you’re very, very lucky. (I’d wager that finding native gold was a lot easier in 1851 than in 2006!)

ANALYSIS OF NATIVE GOLD

Native gold, or gold as it occurs in its natural state, is usually alloyed with various proportions of metallic silver and copper. The proportions of each are found by the following method:

Process 1 – Digest a given quantity of the metal, say 100 grains, with so much nitro-muriatic acid as to dissolve the whole. During the process, a white flocculent precipitate will fall to the bottom of the vessel, which is the silver in the form of a chloride of that metal. The clear liquid must be decanted, leaving this to be collected, washed, and dried on a filter, and then weighed. The proportion of pure silver may be estimated at three quarters the weight of the chloride.

100 grains is about six and a half grams. That’s about $120 worth, at the time I typed this. (That is why I’m not going to be able to do this particular bit of chemistry in our lab. 🙂 )

Comstock refers to nitro-muriatic acid, which is a mixture of nitric and hydrochloric (muriatic) acids. This mixture is also referred to as aqua regia, and is one of the few solvent mixtures that will dissolve metallic gold.

The chloride of silver produced is commonly known as silver chloride (AgCl), which is indeed three quarters silver by mass. My intro and freshman chemistry students should be able to verify that percentage with no difficulty.


(107.87 g Ag) / (143.12 g AgCl) * 100% = 75.35% Ag

Back to Comstock …

Process 2 – The remaining solution to which the washings of the precipitated silver was added, contains the solutions of gold and copper. On adding a solution of the proto-sulphate of iron, the gold will be precipitated, when the clear liquid must be decanted, and the precipitate washed and dried, and afterwards reduced to the metallic state, by fusion with poitash and borax, as above directed.

We certainly don’t want to throw away the gold, so Comstock advises us to precipitate the gold out of solution using “the proto-sulphate of iron”, known today as iron(II) sulfate (FeSO4). I suspect that the iron(II) reduces the gold ions to metallic gold, forming a precipitate of gold and leaving iron(III) behind in solution.

3Fe2+(aq) + Au3+(aq) --> 3Fe3+(aq) + Au(s)

Comstock then has us mix the gold with potash (potassium hydroxide) and borax (sodium borate), then heat in a silver crucible. I’m not entirely certain how this one works, having never had the opportunity to try it.

Process 3 – The liquor now remaining contains the copper and the little iron which was added for the separation of the gold. Of the iron, no account is to be taken, but the copper is to be precipitated by inserting in the liquor clean plates of iron, and heating the solution, when the plates will be covered with metallic copper, the weight of which may be ascertained by first weighing the plates, and then finding out how much they have gained. If any of the copper falls to the bottom of the vessel, this must, after washing and drying, be added to that on the plates.

The weight of each metal thus obtained, will, of course, show the proportions in the mass.

To get the copper out of solution, Constock relies on good old iron. Iron, being a more active metal than copper, will replace copper in solution, causing the copper metal to fall out of solution and coat the iron plates. Freshman chemistry and high school students will be familiar with this kind of reaction too – a single replacement reaction, which might go something like this.

Fe(s) + Cu2+(aq) --> Fe2+(aq) + Cu(s)

Here’s what that might look like, using an iron nail in a solution containing copper ion.

Before heating
[Iron nail in copper solution, before heating]
Copper(II) ion in solution gives it the blue color you see now. The reaction is slow. You can see a little copper metal coating the nail, but there is still a lot of copper ion left in the solution. This was taken about 15-20 minutes after the nail was dropped into the tube.

There seems to be a problem here, though. Since some of the iron from the plates replaces copper in the solution, the plates contain less iron after the reation than they did before. Merely subtracting the final and initial weight of the iron plates neglects the loss of iron to the solution. Since copper, atom for atom, weighs more than iron does, the plates will always gain mass when put into the solution, but the overall amount of copper reported will always be too low, unless I’m missing something.

Still, a rather interesting (if expensive) analysis, using some fairly simple and clever chemistry for separating the components of native gold.

That’s MY quilt!

Friday, May 19th, 2006

We don’t really own our things. They are just on a temporary loan from our real masters, the cats.

[Rusty owns this quilt]
Rusty: This is my quilt. I don’t care if Patty thinks it’s hers!

Use Rusty as your backdrop! Ckick here to download [1024×768, 204K].

Comments closed on this post due to spambots.

Celebration time!

Friday, May 19th, 2006

It’s that time of year again – time for college faculty to attempt to line up in a straight line.

[Linear faculty?]
Faculty demonstrate scatter in linear curve fit

It was also time for severe thunderstorms to give us, for the first time in my years here, a cellphone-lighted graduation ceremony. (I’d have said a “candlelight ceremony”, but that would be so 20th century!)

[A dark and stormy night]
It was a dark and stormy night …

But in all seriousness, this is the day we faculty members work for – they day our graduates go out and show the rsst of the world that they learned something – and are better people for their time here at our school.

[March!]
Marching to the stage

Congratulations 2006 graduates! We’re proud of you!

North Carolina cuisine: Holt Lake Seafood and BBQ

Wednesday, May 17th, 2006

[Holt Lake]

While I’m originally from South Carolina, my wife Patty is from North Carolina. So, when we go to see the in-laws, I get to experience a little North Carolina cuisine. One of the places Patty’s folks love to eat is a little seafood / BBQ place called “Holt Lake Bar-B-Que and Seafood”, located on Highway 301 South in Smithfield, NC.

[Holt Lake sign]
Holt Lake’s sign

As you go into Holt Lake seafood, you might need to wait a bit for your eyes to adjust. The place is downright dark on the inside. The picture below has been lightened up a bit, in fact.

[Holt Lake interior]
A view from the table

A few people who have read this blog before are going to be disappointed in me. Although Holt Lake is a BBQ place, I didn’t get BBQ this time. Holt Lake (unlike every other BBQ place I’ve written about so far) doesn’t have a buffet, and I’ve never really been comfortable with access to only a single plate of BBQ. Oh well. But Holt Lake does have a nice seafood special several days out of the week: All-you-can-eat baby flounder filet with two sides for $6.

Before you start your meal, you’re invited to fill up on hush puppies.

[Hush puppies]
Hush puppies!

The hush puppies are good, but save some room for the flounder! Here’s my plate – flounder filet with fries and potato salad.

[Rick's plate]
Rick’s plate

The potato salad’s very good. The fish was brought out nice and hot (extremely hot – watch out when you first get your plate). The filets are thin, and the fish had a good flavor. Unlike a lot of the places in our town, the food wasn’t overly greasy.

The waitress kept the fish coming fast enough, which is important when you’ve got an all-you-can-eat plate. Unfortunately, the all-you-can-eat is only for the fish, so you can’t refill your potato salad. Save it for last.

Patty had slaw instead of fries (which in retrospect was probably a better choice than mine).

[Patty's plate]
Patty’s plate

If you happen to be going to the outlet stores in Smithfield, Holt Lake is well worth a stop! They’re open Mondays for lunch and Tuesday through Saturday for lunch and dinner.

Read about the BBQ at Holt Lake

Ice cream floats

Monday, May 15th, 2006

From the Wiener Works in Fayetteville, NC:

[Ice cream floats for a limited time]
… until it melts. Then it doesn’t float any more.

How to annoy your teacher

Thursday, May 11th, 2006

Warning – rant coming up!

Occasionally, at the end of the semester, I will get e-mails like this:

I just looked up the grade and saw that I had a “D”. I would like to talk with you face to face and see if there is anything that I can do to get a “C”. Please let me know.

As an instructor, this is probably one of the most annoying kinds of e-mails I ever receive. It’s more annoying than finding out you have a 7:30 AM meeting on the same day you have a night class that meets until 11 PM. It’s more annoying than the bazillion e-mails generated by my blog software when a spambot hits my filters – et cetera.

Why are these sorts of e-mails so annoying? Look at what the student it actually saying. The student isn’t saying that I made an error calculating grades or anything like that. The student knows full well that (s)he earned a “D”, and would like me to just, well, “give” out a grade that wasn’t earned – to certify that a student has certain knowledge when I know (s)he doesn’t.

That’s insulting, because it implies that the student thinks that I am dishonest enough to simply change a student’s grade because they whine loudly enough.

If you’re a student reading this, let me clue you in – most of us instructor types value our integrity. We will do our best to help you earn a good grade in our courses. We will sit with you in our offices or in the lab and help you wrap your head around the course material. Many of us offer nearly 24-hour-a-day access via e-mail, if you need help outside of school hours. At the end of the term, we will record a grade that is in line with your mastery of the course content. If you do “D” work, you’ll get a “D”. If you do “A” work, you’ll get an “A”. Very simple. if we screw up calculating your grade, we’ll correct it – but we won’t just “give you a C” if you flunked. So don’t ask.

This concludes the rant.

Past its prime

Sunday, May 7th, 2006

Here’s part of the menu from one of our local restaurants:

[Benton's]
[Once fresh filet]

Call me crazy, but I think I’d rather have had the grilled chicken breast when it was still fresh.